Konverze plynných a kapalných uhlovodíků a organických látek v proudu termického plazmatu vodní páry a CO2
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ID projektu: | GA15-19444S | Poskytovatel: | Grantová agentura České republiky | Období: | 01.01.2015 - 31.12.2017 | Hlavní řešitel: | doc. RNDr. Milan Hrabovský, CSc. | Cíle projektu: Teoreticky a experimentálně bude studována plazmová konverze metanu, etanolu, metanolu, pyrolýzního oleje a dalších organických látek na
vodík a syntézní plyn reakcí s plazmatem vodní páry a CO2, generovaným ve světově unikátním vodním plazmatronu. Výkon plazmatu je
téměř o dva řády vyšší než u dosud publikovaných plazmových procesů. Další inovace projektu je dána faktem, že reakční plyny, tj. vodní
pára a CO2, budou dodávány do reakčního objemu ve formě plazmatu, tj. disociovány, ionizovány a s přítomností radikálů. Budou proto
vytvořeny podmínky pro snížení spotřeby energie a vyšší účinnost a rychlost konverze. Výzkum zahrne studium interakce plazmatu s
reaktanty v podmínkách změny fáze a chemického složení, analýzu rychlosti procesů a chemické kinetiky a stanovení vlivu podmínek na
vlastnosti a složení produktů reakce. Teoretické modelování zahrne výpočty složení, termodynamických a transportních vlastností produktů
reakcí, modelování proudění plynů a plazmatu a modelování kinetiky procesů. | Související výsledky: | Serov A., Hrabovský M., Kopecký V., Mašláni A., Hlína M., Hurba O.: Lignite Gasification in Thermal Steam Plasma. Plasma Chemistry and Plasma Processing 39 [2] (2019) 395-406. [ Link ] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Bartlová M., Aubrecht V., Murphy A.B.: Modeling of inhomogeneous mixing of plasma species in argon–steam arc discharge. Journal of Physics D-Applied Physics 51 [4] (2018) č. článku 045202. [ Link ] |
Ondáč P., Mašláni A., Hrabovský M., Jeništa J.: Measurement of Anode Arc Attachment Movement in DC Arc Plasma Torch at Atmospheric Pressure. Plasma Chemistry and Plasma Processing 38 [3] (2018) 637-654. [ Link ] |
Hrabovský M., Hlína M., Kopecký V., Mašláni A., Křenek P., Serov A., Hurba O.: Steam Plasma Methane Reforming for Hydrogen Production. Plasma Chemistry and Plasma Processing 38 [4] (2018) 743-758. [ Link ] |
Ondáč P., Mašláni A., Hrabovský M.: Measuring of Mean Plasma Electrical Conductivity in Anode Area of Plasma Torches with an External Anode. Proceedings of the 26th Annual Student Conference Week of Doctoral Students 2017 - WDS 2017. Prague: MATFYZPRESS, 2017 - (Šafránková, J.; Pavlů, J.), s. 88-93. ISBN 978-80-7378-356-3. [ Link ] [WDS´2017 - 26th Annual Student Conference Week of Doctoral Students 2017 /26./. Prague (CZ), 06.06.2017-08.06.2017] |
Mašláni A., Sember V., Hrabovský M.: Spectroscopic determination of temperatures in plasmas generated by arc torches. Spectrochimica Acta Part B: Atomic Spectroscopy 133 [July] (2017) 14-20. [ Link ] |
Hrabovský M., Hlína M., Kopecký V., Mašláni A., Živný O., Křenek P., Serov A., Hurba O.: Steam Plasma Treatment of Organic Substances for Hydrogen and Syngas Production. Plasma Chemistry and Plasma Processing 37 [3] (2017) 739-762. [ Link ] |
Jeništa J.: Steam torch plasma modelling. Plasma Chemistry and Plasma Processing 37 [3] (2017) 653-687. [ Link ] |
Hrabovský M., Hlína M., Kopecký V., Mašláni A., Serov A., Hurba O.: Thermal Plasma Methane Reforming for Hydrogen Production. ISPC 2017: 23rd International Symposium on Plasma Chemistry, Book of extended abstracts. Montréal: International Plasma Chemistry Society, 2017, s. 834-837. ISPC. ISBN N. ISSN N. [ Link ] [ISPC 2017: International Symposium on Plasma Chemistry /23./. Montréal (CA), 30.07.2017-04.08.2017] |
Serov A., Hrabovský M., Kopecký V., Mašláni A., Hlína M.: Conversion of a lignite into a synthetic gas using water-stabilized plasma torch. ISPC 2017: 23rd International Symposium on Plasma Chemistry, Book of extended abstracts. Montréal: International Plasma Chemistry Society, 2017, s. 685-686. ISPC. ISBN N. ISSN N. [ Link ] [ISPC 2017: International Symposium on Plasma Chemistry /23./. Montréal (CA), 30.07.2017-04.08.2017] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Bartlová M., Aubrecht V., Murphy A.B.: On the effect of inhomogeneous mixing of plasma species in argon-steam arc discharge. ISPC 23-Book of Extended Abstracts. Montreal: International Plasma Chemistry Society, 2017, s. 756-759. ISPC. ISBN N. ISSN N. [International Symposium on Plasma Chemistry (ISPC 23)/23./. Montreal (CA), 30.07.2017-04.08.2017] |
Hurba O., Hrabovský M.: Diagnostics of vicinity of thermal plasma jet by electric probes. Proceedings of the XXXIII INTERNATIONAL CONFERENCE ON PHENOMENA IN IONIZED GASES (ICPIG 2017). Lisboa: Instituto de Plasmas e Fusao Nuclear, Instituto Superior Técnico, Universidade de Lisboa, 2017 - (Lemos Alves, L.; Tejero-del-Caz, A.), s. 282. ICPIG. ISBN N. ISSN N. [International Conference on Phenomena in Ionized Gases (ICPIG2017)/33./. Estoril / Lisbon (PT), 09.07.2017-14.07.2017] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Effect of Inhomogeneous Mixing of Plasma Species on the Properties of Argon-Steam Arc Discharge. Proceedings of the 17th International Symposium on Advanced Fluid Information (AFI 2017). Sendai: Tohoku University, 2017, s. 194-195. ISBN N. ISSN 1344-2236. [International Symposium on Advanced Fluid Information (AFI 2017)/17./. Sendai (JP), 01.11.2017-03.11.2017] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Numerical Modeling of Diffusion of Plasma Species in Argon-Water Arc Discharge: Comparison Between Inhomogeneous and Homogeneous Mixing Assumptions. 14th International Conference on Flow Dynamics (ICFD2017) - Proceedings. Sendai: Institute of Fluid Science, Tohoku University, 2017, s. 612-613. ICFD. ISBN N. ISSN N. [International Conference on Flow Dynamics (ICFD2017) /14./. Sendai (JP), 01.11.2017-03.11.2017] |
Hurba O., Hrabovský M.: Application of Electric Probes for Study of Structure of Thermal Plasma Jet. Proceedings of the 26th Annual Student Conference Week of Doctoral Students 2017 - WDS 2017. Prague: MATFYZPRESS, 2017 - (Šafránková, J.), č. článku f2. WDS´. ISBN N. [WDS´2017 - 26th Annual Student Conference Week of Doctoral Students 2017 /26./. Prague (CZ), 06.06.2017-08.06.2017] |
Mašláni A., Ondáč P., Sember V., Hrabovský M.: Time-resolved optical and spectroscopic study of the restrike mode in arc plasma torch. ISPC 2017: 23rd International Symposium on Plasma Chemistry, Book of extended abstracts. Montréal: International Plasma Chemistry Society, 2017, s. 640-642. ISPC. ISBN N. ISSN N. [ Link ] [ISPC 2017: International Symposium on Plasma Chemistry /23./. Montréal (CA), 30.07.2017-04.08.2017] |
Ondáč P., Mašláni A., Hrabovský M., Jeništa J., Sember V.: Measuring of mean electrical conductivity of a plasma volume in hot anode area of DC arc plasma torches. EPS 2017: 44th European Physical Society Conference on Plasma Physics. Vol. 41F. Mulhouse: European Physical Society, 2017 - (Fajardo, M.; Westerhof, E.; Riconda, C.; Melzer, A.; Bret, A.; Dromey, B.), č. článku O2.306. Europhysics Conference Abstracts (ECA). ISBN 979-10-96389-07. [EPS 2017 Conference on Plasma Physics/44./. Belfast (IE), 26.06.2017-30.06.2017] |
Ondáč P., Mašláni A., Hrabovský M.: Investigation of the Arc-Anode Attachment Area by Utilizing a High-Speed Camera. Plasma Physics and Technology 3 [1] (2016) . [ Link ] |
Agon N., Hrabovský M., Chumak O., Hlína M., Kopecký V., Mašláni A., Bosmans A., Helsen L., Skoblja S., Van Oost G., Vierendeels J.: Plasma gasification of refuse derived fuel in a single-stage system using different gasifying agents. Waste Management 47 [January] (2016) 246-255. [ Link ] |
Mašláni A., Sember V., Hrabovský M.: OH emission spectra in recombining arc plasma jet. Proceedings of the 21st International Conference on Gas Discharges and their Applications. Nagoya: Nagoya University, 2016 - (Yokomizu, Y.; Kojima, H.), s. 13-16. GD2016. ISBN N. [GD2016 - International Conference on Gas Discharges and their Applications/21./. Nagoya (JP), 11.09.2016-16.09.2016] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Numerical Modeling of Mixing of Plasma Species in Argon–Water Arc Discharge for Low to Moderate Currents. 13th International Conference on Flow Dynamics (ICFD2016) - Proceedings. Sendai: Institute of Fluid Science, Tohoku University, 2016, s. 562-563. ISBN N. [ Link ] [International Conference on Flow Dynamics (ICFD2016) /13./. Sendai (JP), 10.10.2016-12.10.2016] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Investigation of diffusion of plasma species in argon-steam arc discharge. Proceedings of the 16th International Symposium on Advanced Fluid Information (AFI 2016). Sendai: Institute of Fluid Science, Tohoku University, 2016, s. 174-175. ISBN N. [ Link ] [The Sixteenth International Symposium on Advanced Fluid Information (AFI-2016) /16./. Sendai (JP), 10.10.2016-12.10.2016] |
Hrabovský M.: Plasma Gasification of Organic Waste and Biomass, chapter 7. Plasma Combustion, Gasification, and Pollution Control volume 2: Combustion and Gasification. Denver Colorado: Outskirts Press, Inc., 2016 - (Matveev, I.), s. 418-446. ISBN 978-1-4787-6920-0 |
Brom P., Brožek V., Březina V., Hlína M., Mastný L., Novák M.: Photocatalytic Decomposition of Wastewater from the Production of Explosives. Proceedings of the 4th International Conference on Chemical Technology. Prague: Czech Society of Industrial Chemistry, 2016 - (Veselý, M.; Hrdlička, Z.; Hanika, J.; Lubojacký, J.), s. 176-180. ICCT. ISBN 978-80-86238-94-4. ISSN 2336-811X. [ Link ] [International Conference on Chemical Technology, ICCT2016 /4./. Mikulov (CZ), 25.04.2016-27.04.2016] |
Hurba O., Hlína M., Hrabovský M.: Diagnostics of Plasma Jet Generated in Water/Argon DC Arc Torch. Plasma Physics and Technology 3 [1] (2016) 5-8. [Symposium on Physics of Switching Arc 2015, FSO 2015 /21./. Nové Město na Moravě, 07.09.2015-11.09.2015] |
Ondáč P., Mašláni A., Hrabovský M.: Arc-anode attachment area in DC arc plasma torch. The 14th High-Tech Plasma Processes Conference (HTPP 14). Munich: Universität der Bunderwehr München, 2016, s. 127-128. ISBN N. [High-Tech Plasma Processes Conference (HTPP 2016)/14./. Munich (DE), 03.07.2016-07.07.2016] |
Ondáč P., Mašláni A., Hrabovský M.: Arc–Anode Attachment Area in DC Arc Plasma Torch at Low Pressure. Proceedings of the 25th Annual Conference of Doctoral Students – WDS 2016. Prague: MATFYZPRESS Prague, 2016 - (Šafránková, J.; Pavlů, J.), s. 132-136. WDS´. ISBN 978-80-7378-333-4. [ Link ] [WDS´2016 - 25th Annual Student Conference Week of Doctoral Students 2016. Prague (CZ), 07.06.2016-09.06.2016] |
Hlína M., Hrabovský M., Kopecký V., Mašláni A., Chráska T.: Plasma decomposition of pyrolysis oil to synthesis gas and carbon black. ISPC 22 - 22nd International Symposium on Plasma Chemistry. Antwerp : International Plasma Chemistry Society, 2015, P-III-9-15-P-III-9-15. ISBN N. [ Link ] [ISPC 22 - 22nd International Symposium on Plasma Chemistry/22./. Antwerp (BE), 05.07.2015-10.07.2015] |
Hurba O., Hrabovský M., Gregor J.: Electric probe diagnostics of low pressure dc arc steam-argon plasma jet. ISPC 22 - 22nd International Symposium on Plasma Chemistry. Antwerp : International Plasma Chemistry Society, 2015, P-II-12-7-P-II-12-7. ISBN N. [ Link ] [ISPC 22 - 22nd International Symposium on Plasma Chemistry/22./. Antwerp (BE), 05.07.2015-10.07.2015] |
Hlína M., Hrabovský M.: Enthalpy Probe Diagnostics of Steam/Argon Plasma Jet. Plasma Physics and Technology 2 [2] (2015) 142-145. [ Link ] [Symposium on Physics of Switching Arc/21./. Nové Město na Moravě, 07.09.2015-11.09.2015] |
Mašláni A., Sember V.: Interpretation of temperatures from emission spectra in thermal arc plasmas. 32nd International Conference on Phenomena in Ionized Gases (ICPIG) Book of abstracts. Vol. 32. Iasi : Alexandru Ioan Cuza University of Iasi, 2015 - (Popa, G.) ISBN N. - (ICPIG. 32). [ Link ] [International Conference on Phenomena in Ionized Gases -ICPIG 2015/32./. Iasi (RO), 26.07.2015-31.07.2015] |
Mašláni A., Sember V., Hrabovský M.: Measurement of Copper Vapors in Water-Argon Thermal Plasma Jet. Plasma Physics and Technology 2 [2] (2015) 159-162. [ Link ] [Symposium on Physics of Switching Arc/21./. Nové Město na Moravě, 07.09.2015-11.09.2015] |
Agon N., Chumak O., Hrabovský M.: Single-stage plasma gasification of RDF. ISPC 22 - 22nd International Symposium on Plasma Chemistry. Antwerp : International Plasma Chemistry Society, 2015, O-19-1-O-19-1. ISBN N. [ Link ] [ISPC 22 - 22nd International Symposium on Plasma Chemistry/22./. Antwerp (BE), 05.07.2015-10.07.2015] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Hrabovský M., Murphy A.B., Bartlová M., Aubrecht V.: Investigation of inhomogeneous mixing of plasma species in a hybrid-stabilized argon-water arc discharge: The very first simulations. Proceedings of the 15th International Symposium on Advanced Fluid Information (AFI 2015). Sendai : Tohoku University, 2015, s. 56-57. ISSN 1344-2236. [ Link ] [International Symposium on Advanced Fluid Information (AFI 2015)/15./. Sendai (JP), 27.10.2015-29.10.2015] |
Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Preliminary Study of Mixing of Plasma Species in a Hybrid-Stabilized Argon-Water Electric Arc. Plasma Physics and Technology 2 [3] (2015) 316-319. [Symposium on Physics of Switching Arc/21./. Nové Město na Moravě, 07.09.2015-11.09.2015] |
Agon N., Vierendeels J., Hrabovský M., Murphy A.B., Van Oost G.: Interaction of a H2O/Ar Plasma Jet with Nitrogen Atmosphere: Effect of the Method for Calculating Thermophysical Properties of the Gas Mixture on the flow field. Plasma Chemistry and Plasma Processing 35 [2] (2015) 365-386. [ Link ] |
Ondáč P., Mašláni A., Hrabovský M.: Investigation of Anode Attachment Area in Water/Argon Stabilized Plasma Arc. WDS 2015 — Proceedings of Contributed Papers — Physics. Prague : MATFYZPRESS, 2015 - (Šafránková, J.; Pavlů, J.), s. 245-251 ISBN 978-80-7378-311-2. - (WDS). [ Link ] [WDS - 2015 - 24th Annual Conference of Doctoral Students/24./. Prague (CZ), 02.06.2015-04.06.2015] |
Hrabovský M., van der Walt I.J.: Plasma Waste Destruction. Handbook of Thermal Science and Engineering. 1. New York: Springer International Publishing AG, 2018 - (Kulacki, F.), s. 1-57. Part of Springer Nature. ISBN 978-3-319-32003-8 [ Link ] |
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