Reforming of gas and liquid hydrocarbons and organics in steam and CO2 thermal plasma jets
Project ID:GA15-19444S
Provider:Czech Science Foundation
Period:Jan 01, 2015 - Dec 31, 2017
Principal Investigator:doc. RNDr. Milan Hrabovský, CSc.

Aims of the project: Steam and dry (CO2) reforming of methane, ethanol, methanol, pyrolysis oil, and other organics in thermal plasma generated in the world unique water stabilized plasma torch will be studied both theoretically and experimentally. The plasma power will be almost two orders higher compared with published experiments on plasma reforming. The second innovation of this project follows from the fact that reaction gases (steam and CO2) will be supplied into reaction volume in the state of plasma, i.e. dissociated, ionized and with presence of radicals. Lower energy consumption and higher conversion rate in these conditions are supposed. The research includes investigation of interaction of plasma jet with reactants in conditions of changes of state and chemical composition, study of process rate and kinetics, and determination of effect of conditions on properties of process products. The theoretical modeling involve computations of composition and properties of reaction products, fluid flow modeling of mixing of plasma with reactants and modeling of kinetics of the processes.

Results:

Serov A., Hrabovský M., Kopecký V., Mašláni A., Hlína M., Hurba O.: Lignite Gasification in Thermal Steam Plasma. Plasma Chemistry and Plasma Processing 39 [2] (2019) 395-406. [ Abstract ] [ Link ]

Jeništa J., Takana H., Uehara S., Nishiyama H., Bartlová M., Aubrecht V., Murphy A.B.: Modeling of inhomogeneous mixing of plasma species in argon–steam arc discharge. Journal of Physics D-Applied Physics 51 [4] (2018) č. článku 045202. [ Abstract ] [ Link ]

Ondáč P., Mašláni A., Hrabovský M., Jeništa J.: Measurement of Anode Arc Attachment Movement in DC Arc Plasma Torch at Atmospheric Pressure. Plasma Chemistry and Plasma Processing 38 [3] (2018) 637-654. [ Abstract ] [ Link ]

Hrabovský M., Hlína M., Kopecký V., Mašláni A., Křenek P., Serov A., Hurba O.: Steam Plasma Methane Reforming for Hydrogen Production. Plasma Chemistry and Plasma Processing 38 [4] (2018) 743-758. [ Abstract ] [ Link ]

Ondáč P., Mašláni A., Hrabovský M.: Measuring of Mean Plasma Electrical Conductivity in Anode Area of Plasma Torches with an External Anode. Proceedings of the 26th Annual Student Conference Week of Doctoral Students 2017 - WDS 2017. Prague: MATFYZPRESS, 2017 - (Šafránková, J.; Pavlů, J.), s. 88-93. ISBN 978-80-7378-356-3. [ Abstract ] [ Link ]
[WDS´2017 - 26th Annual Student Conference Week of Doctoral Students 2017 /26./. Prague (CZ), 06.06.2017-08.06.2017]

Mašláni A., Sember V., Hrabovský M.: Spectroscopic determination of temperatures in plasmas generated by arc torches. Spectrochimica Acta Part B: Atomic Spectroscopy 133 [July] (2017) 14-20. [ Abstract ] [ Link ]

Hrabovský M., Hlína M., Kopecký V., Mašláni A., Živný O., Křenek P., Serov A., Hurba O.: Steam Plasma Treatment of Organic Substances for Hydrogen and Syngas Production. Plasma Chemistry and Plasma Processing 37 [3] (2017) 739-762. [ Abstract ] [ Link ]

Jeništa J.: Steam torch plasma modelling. Plasma Chemistry and Plasma Processing 37 [3] (2017) 653-687. [ Abstract ] [ Link ]

Hrabovský M., Hlína M., Kopecký V., Mašláni A., Serov A., Hurba O.: Thermal Plasma Methane Reforming for Hydrogen Production. ISPC 2017: 23rd International Symposium on Plasma Chemistry, Book of extended abstracts. Montréal: International Plasma Chemistry Society, 2017, s. 834-837. ISPC. ISBN N. ISSN N. [ Abstract ] [ Link ]
[ISPC 2017: International Symposium on Plasma Chemistry /23./. Montréal (CA), 30.07.2017-04.08.2017]

Serov A., Hrabovský M., Kopecký V., Mašláni A., Hlína M.: Conversion of a lignite into a synthetic gas using water-stabilized plasma torch. ISPC 2017: 23rd International Symposium on Plasma Chemistry, Book of extended abstracts. Montréal: International Plasma Chemistry Society, 2017, s. 685-686. ISPC. ISBN N. ISSN N. [ Abstract ] [ Link ]
[ISPC 2017: International Symposium on Plasma Chemistry /23./. Montréal (CA), 30.07.2017-04.08.2017]

Jeništa J., Takana H., Uehara S., Nishiyama H., Bartlová M., Aubrecht V., Murphy A.B.: On the effect of inhomogeneous mixing of plasma species in argon-steam arc discharge. ISPC 23-Book of Extended Abstracts. Montreal: International Plasma Chemistry Society, 2017, s. 756-759. ISPC. ISBN N. ISSN N. [ Abstract ]
[International Symposium on Plasma Chemistry (ISPC 23)/23./. Montreal (CA), 30.07.2017-04.08.2017]

Hurba O., Hrabovský M.: Diagnostics of vicinity of thermal plasma jet by electric probes. Proceedings of the XXXIII INTERNATIONAL CONFERENCE ON PHENOMENA IN IONIZED GASES (ICPIG 2017). Lisboa: Instituto de Plasmas e Fusao Nuclear, Instituto Superior Técnico, Universidade de Lisboa, 2017 - (Lemos Alves, L.; Tejero-del-Caz, A.), s. 282. ICPIG. ISBN N. ISSN N. [ Abstract ]
[International Conference on Phenomena in Ionized Gases (ICPIG2017)/33./. Estoril / Lisbon (PT), 09.07.2017-14.07.2017]

Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Effect of Inhomogeneous Mixing of Plasma Species on the Properties of Argon-Steam Arc Discharge. Proceedings of the 17th International Symposium on Advanced Fluid Information (AFI 2017). Sendai: Tohoku University, 2017, s. 194-195. ISBN N. ISSN 1344-2236. [ Abstract ]
[International Symposium on Advanced Fluid Information (AFI 2017)/17./. Sendai (JP), 01.11.2017-03.11.2017]

Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Numerical Modeling of Diffusion of Plasma Species in Argon-Water Arc Discharge: Comparison Between Inhomogeneous and Homogeneous Mixing Assumptions. 14th International Conference on Flow Dynamics (ICFD2017) - Proceedings. Sendai: Institute of Fluid Science, Tohoku University, 2017, s. 612-613. ICFD. ISBN N. ISSN N. [ Abstract ]
[International Conference on Flow Dynamics (ICFD2017) /14./. Sendai (JP), 01.11.2017-03.11.2017]

Hurba O., Hrabovský M.: Application of Electric Probes for Study of Structure of Thermal Plasma Jet. Proceedings of the 26th Annual Student Conference Week of Doctoral Students 2017 - WDS 2017. Prague: MATFYZPRESS, 2017 - (Šafránková, J.), č. článku f2. WDS´. ISBN N. [ Abstract ]
[WDS´2017 - 26th Annual Student Conference Week of Doctoral Students 2017 /26./. Prague (CZ), 06.06.2017-08.06.2017]

Mašláni A., Ondáč P., Sember V., Hrabovský M.: Time-resolved optical and spectroscopic study of the restrike mode in arc plasma torch. ISPC 2017: 23rd International Symposium on Plasma Chemistry, Book of extended abstracts. Montréal: International Plasma Chemistry Society, 2017, s. 640-642. ISPC. ISBN N. ISSN N. [ Abstract ] [ Link ]
[ISPC 2017: International Symposium on Plasma Chemistry /23./. Montréal (CA), 30.07.2017-04.08.2017]

Ondáč P., Mašláni A., Hrabovský M., Jeništa J., Sember V.: Measuring of mean electrical conductivity of a plasma volume in hot anode area of DC arc plasma torches. EPS 2017: 44th European Physical Society Conference on Plasma Physics. Vol. 41F. Mulhouse: European Physical Society, 2017 - (Fajardo, M.; Westerhof, E.; Riconda, C.; Melzer, A.; Bret, A.; Dromey, B.), č. článku O2.306. Europhysics Conference Abstracts (ECA). ISBN 979-10-96389-07. [ Abstract ]
[EPS 2017 Conference on Plasma Physics/44./. Belfast (IE), 26.06.2017-30.06.2017]

Ondáč P., Mašláni A., Hrabovský M.: Investigation of the Arc-Anode Attachment Area by Utilizing a High-Speed Camera. Plasma Physics and Technology 3 [1] (2016) . [ Abstract ] [ Link ]

Agon N., Hrabovský M., Chumak O., Hlína M., Kopecký V., Mašláni A., Bosmans A., Helsen L., Skoblja S., Van Oost G., Vierendeels J.: Plasma gasification of refuse derived fuel in a single-stage system using different gasifying agents. Waste Management 47 [January] (2016) 246-255. [ Abstract ] [ Link ]

Mašláni A., Sember V., Hrabovský M.: OH emission spectra in recombining arc plasma jet. Proceedings of the 21st International Conference on Gas Discharges and their Applications. Nagoya: Nagoya University, 2016 - (Yokomizu, Y.; Kojima, H.), s. 13-16. GD2016. ISBN N. [ Abstract ]
[GD2016 - International Conference on Gas Discharges and their Applications/21./. Nagoya (JP), 11.09.2016-16.09.2016]

Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Numerical Modeling of Mixing of Plasma Species in Argon–Water Arc Discharge for Low to Moderate Currents. 13th International Conference on Flow Dynamics (ICFD2016) - Proceedings. Sendai: Institute of Fluid Science, Tohoku University, 2016, s. 562-563. ISBN N. [ Abstract ] [ Link ]
[International Conference on Flow Dynamics (ICFD2016) /13./. Sendai (JP), 10.10.2016-12.10.2016]

Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Investigation of diffusion of plasma species in argon-steam arc discharge. Proceedings of the 16th International Symposium on Advanced Fluid Information (AFI 2016). Sendai: Institute of Fluid Science, Tohoku University, 2016, s. 174-175. ISBN N. [ Abstract ] [ Link ]
[The Sixteenth International Symposium on Advanced Fluid Information (AFI-2016) /16./. Sendai (JP), 10.10.2016-12.10.2016]

Hrabovský M.: Plasma Gasification of Organic Waste and Biomass, chapter 7. Plasma Combustion, Gasification, and Pollution Control volume 2: Combustion and Gasification. Denver Colorado: Outskirts Press, Inc., 2016 - (Matveev, I.), s. 418-446. ISBN 978-1-4787-6920-0 [ Abstract ]

Brom P., Brožek V., Březina V., Hlína M., Mastný L., Novák M.: Photocatalytic Decomposition of Wastewater from the Production of Explosives. Proceedings of the 4th International Conference on Chemical Technology. Prague: Czech Society of Industrial Chemistry, 2016 - (Veselý, M.; Hrdlička, Z.; Hanika, J.; Lubojacký, J.), s. 176-180. ICCT. ISBN 978-80-86238-94-4. ISSN 2336-811X. [ Abstract ] [ Link ]
[International Conference on Chemical Technology, ICCT2016 /4./. Mikulov (CZ), 25.04.2016-27.04.2016]

Hurba O., Hlína M., Hrabovský M.: Diagnostics of Plasma Jet Generated in Water/Argon DC Arc Torch. Plasma Physics and Technology 3 [1] (2016) 5-8. [ Abstract ]
[Symposium on Physics of Switching Arc 2015, FSO 2015 /21./. Nové Město na Moravě, 07.09.2015-11.09.2015]

Ondáč P., Mašláni A., Hrabovský M.: Arc-anode attachment area in DC arc plasma torch. The 14th High-Tech Plasma Processes Conference (HTPP 14). Munich: Universität der Bunderwehr München, 2016, s. 127-128. ISBN N. [ Abstract ]
[High-Tech Plasma Processes Conference (HTPP 2016)/14./. Munich (DE), 03.07.2016-07.07.2016]

Ondáč P., Mašláni A., Hrabovský M.: Arc–Anode Attachment Area in DC Arc Plasma Torch at Low Pressure. Proceedings of the 25th Annual Conference of Doctoral Students – WDS 2016. Prague: MATFYZPRESS Prague, 2016 - (Šafránková, J.; Pavlů, J.), s. 132-136. WDS´. ISBN 978-80-7378-333-4. [ Abstract ] [ Link ]
[WDS´2016 - 25th Annual Student Conference Week of Doctoral Students 2016. Prague (CZ), 07.06.2016-09.06.2016]

Hlína M., Hrabovský M., Kopecký V., Mašláni A., Chráska T.: Plasma decomposition of pyrolysis oil to synthesis gas and carbon black. ISPC 22 - 22nd International Symposium on Plasma Chemistry. Antwerp : International Plasma Chemistry Society, 2015, P-III-9-15-P-III-9-15. ISBN N. [ Abstract ] [ Link ]
[ISPC 22 - 22nd International Symposium on Plasma Chemistry/22./. Antwerp (BE), 05.07.2015-10.07.2015]

Hurba O., Hrabovský M., Gregor J.: Electric probe diagnostics of low pressure dc arc steam-argon plasma jet. ISPC 22 - 22nd International Symposium on Plasma Chemistry. Antwerp : International Plasma Chemistry Society, 2015, P-II-12-7-P-II-12-7. ISBN N. [ Abstract ] [ Link ]
[ISPC 22 - 22nd International Symposium on Plasma Chemistry/22./. Antwerp (BE), 05.07.2015-10.07.2015]

Hlína M., Hrabovský M.: Enthalpy Probe Diagnostics of Steam/Argon Plasma Jet. Plasma Physics and Technology 2 [2] (2015) 142-145. [ Abstract ] [ Link ]
[Symposium on Physics of Switching Arc/21./. Nové Město na Moravě, 07.09.2015-11.09.2015]

Mašláni A., Sember V.: Interpretation of temperatures from emission spectra in thermal arc plasmas. 32nd International Conference on Phenomena in Ionized Gases (ICPIG) Book of abstracts. Vol. 32. Iasi : Alexandru Ioan Cuza University of Iasi, 2015 - (Popa, G.) ISBN N. - (ICPIG. 32). [ Abstract ] [ Link ]
[International Conference on Phenomena in Ionized Gases -ICPIG 2015/32./. Iasi (RO), 26.07.2015-31.07.2015]

Mašláni A., Sember V., Hrabovský M.: Measurement of Copper Vapors in Water-Argon Thermal Plasma Jet. Plasma Physics and Technology 2 [2] (2015) 159-162. [ Abstract ] [ Link ]
[Symposium on Physics of Switching Arc/21./. Nové Město na Moravě, 07.09.2015-11.09.2015]

Agon N., Chumak O., Hrabovský M.: Single-stage plasma gasification of RDF. ISPC 22 - 22nd International Symposium on Plasma Chemistry. Antwerp : International Plasma Chemistry Society, 2015, O-19-1-O-19-1. ISBN N. [ Abstract ] [ Link ]
[ISPC 22 - 22nd International Symposium on Plasma Chemistry/22./. Antwerp (BE), 05.07.2015-10.07.2015]

Jeništa J., Takana H., Uehara S., Nishiyama H., Hrabovský M., Murphy A.B., Bartlová M., Aubrecht V.: Investigation of inhomogeneous mixing of plasma species in a hybrid-stabilized argon-water arc discharge: The very first simulations. Proceedings of the 15th International Symposium on Advanced Fluid Information (AFI 2015). Sendai : Tohoku University, 2015, s. 56-57. ISSN 1344-2236. [ Abstract ] [ Link ]
[International Symposium on Advanced Fluid Information (AFI 2015)/15./. Sendai (JP), 27.10.2015-29.10.2015]

Jeništa J., Takana H., Uehara S., Nishiyama H., Murphy A.B., Bartlová M., Aubrecht V.: Preliminary Study of Mixing of Plasma Species in a Hybrid-Stabilized Argon-Water Electric Arc. Plasma Physics and Technology 2 [3] (2015) 316-319. [ Abstract ]
[Symposium on Physics of Switching Arc/21./. Nové Město na Moravě, 07.09.2015-11.09.2015]

Agon N., Vierendeels J., Hrabovský M., Murphy A.B., Van Oost G.: Interaction of a H2O/Ar Plasma Jet with Nitrogen Atmosphere: Effect of the Method for Calculating Thermophysical Properties of the Gas Mixture on the flow field. Plasma Chemistry and Plasma Processing 35 [2] (2015) 365-386. [ Abstract ] [ Link ]

Ondáč P., Mašláni A., Hrabovský M.: Investigation of Anode Attachment Area in Water/Argon Stabilized Plasma Arc. WDS 2015 — Proceedings of Contributed Papers — Physics. Prague : MATFYZPRESS, 2015 - (Šafránková, J.; Pavlů, J.), s. 245-251 ISBN 978-80-7378-311-2. - (WDS). [ Abstract ] [ Link ]
[WDS - 2015 - 24th Annual Conference of Doctoral Students/24./. Prague (CZ), 02.06.2015-04.06.2015]

Hrabovský M., van der Walt I.J.: Plasma Waste Destruction. Handbook of Thermal Science and Engineering. 1. New York: Springer International Publishing AG, 2018 - (Kulacki, F.), s. 1-57. Part of Springer Nature. ISBN 978-3-319-32003-8 [ Abstract ] [ Link ]