Study of nonequilibrium kinetics of plasmachemical reactions in atmospheric gases at reduced pressure for applications in analytical chemistry
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Project ID: | GA202/08/1106 | Provider: | Czech Science Foundation | Period: | Jan 01, 2008 - Dec 31, 2010 | Recipient -- coordinator: | Faculty of Chemistry, Brno University of Technology -- Doc. RNDr. František Krčma, Ph.D. | Co-recepient(s) / PI(s): | Institute of Plasma Physics, Czech Academy of Sciences, Prague -- RNDr. Milan Šimek Faculty of Natural Sciences, Masaryk University in Brno -- Prof. RNDr. Viktor Kanický, DrSc.
| Aims of the project: The proposed project is focused on the study of kinetic processes taking place during discharges and the post-discharge in nitrogen and its mixtures with oxygen and argon with some traces. The radiofrequency and microwave plasma sources (both in continuous and pulsed regime) will be designed to create the discharges at moderate pressures up to atmospheric pressure. The low pressure DC discharge will be used as the reference for kinetic study. The plasmas will be observed by optical emission and absorption spectroscopies including the spectra numeric simulations and in-situ ESR spectroscopy. The vibrationally state-specified model of the discharge and post-discharge kinetics will be created and confronted with the experimental results. As the direct application the chemical analysis of selected elements is proposed and thus the new techniques of analytic sample introduction will be designed. Besides this application, the results could be applied in fields of plasma sterilization, surface | Results: | Šimek M., Ambrico P. F., Prukner V.: ICCD microscopic imaging of a single micro-discharge in surface coplanar DBD geometry: determination of the luminous diameter of N-2 and Ar streamers. Plasma Sources Science & Technology 20 [2] (2011) 025010-025010. [ Abstract ] [ Link ] [European Sectional Conference on Atomic and Molecular Physics of Ionized Gases (ESCAMPIGXX)/20th./. Novi Sad, SERBIA, 13.07.2010-17.07.2010] |
Šimek M., Prukner V., Schmidt J.: Optical and electrical characteristics of a single surface DBD micro-discharge produced in atmospheric-pressure nitrogen and synthetic air. Plasma Sources Science & Technology 20 [2] (2011) 025009-025009. [ Link ] [European Sectional Conference on Atomic and Molecular Physics of Ionized Gases (ESCAMPIGXX)/20th./. Novi Sad, SERBIA, 13.07.2010-17.07.2010] |
Šimek M., Ambrico P. F., Dilecce G., Prukner V., Schmidt J., De Benedictis S.: N2(A3+u) behaviour in a N2-NO surface dielectric barrier discharge in the modulated ac regime at atmospheric pressure. Journal of Physics D-Applied Physics 43 [12] (2010) 124003-124003. [ Abstract ] [ Link ] |
Šimek M.: ICCD microscopy and spectroscopy of a single surface coplanar DBD micro-discharge driven in N2, O2 and in synthetic air at atmospheric pressure. Book of Contributed Papers of 12th International Symposium on High Pressure Low Temperature Plasma Chemistry. Bratislava : Comenius University, 2010 - (Országh, J.; Papp, P.; Matejčík, Š.) S. 188-192. ISBN 978-80-89186-72-3. [ Abstract ] [ Link ] [International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XII)/12th./. Kúpeľná Dvorana, Trenčianske Teplice (SK), 12.09.2010-17.09.2010] |
Ambrico P. F., Ambrico M., Šimek M., Colaianni A., Dilecce G., De Benedictis S.: Laser triggered single streamer in a pin-to-pin coplanar dielectric barier discharge. Applied Physics Letters 94 [23] (2009) 231501-231501. [ Abstract ] [ Link ] |
Ambrico P. F., Šimek M., Dilecce G., De Benedictis S.: N-2(A(3)Sigma(+)(u)) time evolution in N-2 atmospheric pressure surface dielectric barrier discharge driven by ac voltage under modulated regime. Applied Physics Letters 94 [23] (2009) 231503-231503. [ Abstract ] [ Link ] |
Šimek M., Prukner V., Schmidt J.: Optical and electrical characteristics of N2 microdischarges produced in coplanar surface DBD geometry. Bulletin of the American Physical Society 53 [10] (2008) 60-60. [ Abstract ] [The 61st Annual Gaseous Electronic Conference. Dallas,Texas, 13.10.2008-17.10.2008] |
Domlátil J., Brožek V., Huber Š., Hlína M., Hrabovský M.: Degradace ve vodě rozpustných organických látek. Odpadové fórum 2008 – sborník přednášek. Praha : IT Design Praha, UTAX Praha, 2008. S. 3276-3280. ISBN 978-80-02-02011-0. - (1). [ Abstract ] [Aprochem 2008. Milovy (CZ), 16.04.2008-18.04.2008] |
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